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GATE 2017-2018 :: GATE Chemistry

  1. The angular part of the wavefunction for the electron in a hydrogen atom is proportional to sin2θ cos θ e2iØ . The values of the azimuthal quantum number (l) and the magnetic quantum number (m) are, respectively
  2. A.
    2 and 2
    B.
    2 and "“2
    C.
    3 and 2
    D.
    3 and -2

  3. T he bond that gives the most intense band in the infrared spectrum for its stretching vibration is
  4. A.
    C─H
    B.
    N─H
    C.
    O─H
    D.
    S─H

  5. I f xA and xB are the respective mole fractions of A and B in an ideal solution of the two and TA, TB, T are the fusion temperatures of pure A, pure B and the ideal solution respectively, then
  6. A.
    .

    B.
    .

    C.
    .

    D.
    .


  7. F or a reaction involving two steps given below

    assume that the first step attains equilibrium rapidly. The rate of formation of P is proportional to
  8. A.
    [G
    B.
    [G
    C.
    [G
    D.
    [G

  9. A metal chelate that can be used for separation and quantitative analysis of aluminium ions by gas chromatography is
  10. A.
    EDTA
    B.
    ethylene glycol
    C.
    dinonyl phthalate
    D.
    trifluoroacetylacetone

  11. The enthalpies of hydration of Ca2+, Mn2+ and Zn2+ follow the order
  12. A.
    Mn2+ > Ca2+ > Zn2+
    B.
    Zn2+ > Ca2+ > Mn2+
    C.
    Mn2+ > Zn2+ > Ca2+
    D.
    Zn2+ > Mn2+ > Ca2+

  13. The number of terminal carbonyl groups present in Fe2(CO)9 is
  14. A.
    2
    B.
    5
    C.
    6
    D.
    3

  15. Among the following substituted silanes, the one that gives cross-linked silicone polymer upon hydrolysis is
  16. A.
    (CH3)4Si
    B.
    CH3SiCl3
    C.
    (CH3)2SiCl2
    D.
    (CH3)3SiCl

  17. The plot of χT versus T ((where χ is molar magnetic susceptibility and T is the temperature) for a paramagnetic complex which strictly follows Curie equation is
  18. A.
    .

    B.
    .

    C.
    .

    D.
    .


  19. A mong the following donors, the one that forms most stable adduct with the Lewis acid B(CH3)3 is
  20. A.
    4-methylpyridine
    B.
    2,6-dimethylpyridine
    C.
    4-nitropyridine
    D.
    2,6-di-tert-butylpyridine