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  1. In case of a reversible process (following pvn = constant), work obtained for trebling the volume (v₁ = 1 m³ and v₂ 3 m³ ) is max imum, when the value of 'n' is

  2. A.

     0

    B.

     1

    C.

     1.44

    D.

     1.66


  3. In an adiabatic process, the

  4. A.

     Heat transfer is zero

    B.

     Temperature change is zero

    C.

     Work done is a path function

    D.

     Enthalpy remains constant


  5. Which of the following is not an extensive property?

  6. A.

     Free energy

    B.

     Entropy

    C.

     Refractive index

    D.

     None of these


  7. In an irreversible process

  8. A.

     Tds = dE - dW = 0

    B.

     DE - dW - Tds = 0

    C.

     Tds - dE + dW< 0

    D.

     Tds - dT + dW< 0


  9. In any spontaneous process,

  10. A.

     Only F decreases

    B.

     Only A decreases

    C.

     Both F and A decreases

    D.

     Both F and A increase


  11. The enthalpy change when ammonia gas is dissolved in water is called the heat of

  12. A.

     Solution

    B.

     Formation

    C.

     Dilution

    D.

     Combustion


  13. During adiabatic expansion of gas

  14. A.

     Pressure remains constant

    B.

     Pressure is increased

    C.

     Temperature remains constant

    D.

     None of these


  15. Compound having large heat of formation is

  16. A.

     More stable

    B.

     Less stable

    C.

     Not at all stable (like nascent O₂)

    D.

     Either more or less stable ; depends on the compound


  17. The equation DU = Tds - PdV is applicable to infinitesimal changes occuring in

  18. A.

     An open system of constant composition

    B.

     A closed system of constant composition

    C.

     An open system with changes in composition

    D.

     A closed system with changes in composition


  19. Pick out the correct statement.

  20. A.

     Compression ratio of an Otto engine is comparatively higher than a diesel engine

    B.

     Efficiency of an Otto engine is higher than that of a diesel engine for the same compression ratio

    C.

     Otto engine efficiency decreases with the rise in compression ratio, due to decrease in work produced per quantity of heat

    D.

     Diesel engine normally operates at lower compression ratio than an Otto engine for an equal output of work