Discussion :: Chemical Engineering Thermodynamics
- A closed system is cooled reversibly from 100°C to 50°C. If no work is done on the system
A.
Its internal energy (U) decreases and its entropy (S) increases |
B.
U and S both decreases |
C.
U decreases but S is constant |
D.
U is constant but S decreases |
Answer : Option B
Explanation :
Since here heat is taken from the system Q=−ve
From second law of thermodynamics TdS≥δQ
Since given reversible process TdS=δQ
⇒dS=−ve
From first law of thermodynamics
δQ=dU⇒dU=−ve
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